Reduction of hypervalent chromium in acidic media by alginic acid
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چکیده
منابع مشابه
Reduction of hypervalent chromium in acidic media by alginic acid.
Selective oxidation of carboxylate groups present in alginic acid by Cr(VI) affords CO2, oxidized alginic acid, and Cr(III) as final products. The redox reaction afforded first-order kinetics in [alginic acid], [Cr(VI)], and [H(+)], at fixed ionic strength and temperature. Kinetic studies showed that the redox reaction proceeds through a mechanism which combines Cr(VI)→Cr(IV)→Cr(II) and Cr(VI)→...
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ژورنال
عنوان ژورنال: Carbohydrate Polymers
سال: 2014
ISSN: 0144-8617
DOI: 10.1016/j.carbpol.2014.07.065