Redox Site Confinement in Highly Unsymmetric Dimanganese Complexes
نویسندگان
چکیده
منابع مشابه
Redox site confinement in highly unsymmetric dimanganese complexes.
A set of highly preorganized pyrazolate-bridged dimanganese complexes L(Mn)MnX have been prepared and structurally characterized. They can be described as hybrid organometallic/Werner-type systems that consist of a low-spin CpMn(I)(CO)2 subunit (Mn1) and a proximate tripodal tetradentate {N4} binding pocket accommodating a high-spin Mn(II) ion (Mn2), with Mn...Mn distances of approximately 4.3 ...
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ژورنال
عنوان ژورنال: Inorganic Chemistry
سال: 2005
ISSN: 0020-1669,1520-510X
DOI: 10.1021/ic0503683