Redox dynamics of later Cambrian oceans

نویسندگان

چکیده

A growing body of evidence suggests that the deep oceans during early Paleozoic Era were widely oxygen deficient, despite for increased marine oxygenation Neoproterozoic. However, temporal and geographic extents dynamics reducing conditions within these are not well understood. Here, we investigate redox history Drumian through earliest Jiangshanian International Stages Cambrian Period, using concentrations redox-sensitive metals (vanadium, uranium, molybdenum), iron speciation, Mo isotope stratigraphy Alum Shale Formation Scandinavia. These data suggest a major perturbation occurred in trace metal cycling later Period was linked to transient change coincident with well-known Steptoean Positive Isotope Excursion or SPICE. The ?98Mo measurements shale show systematic variations interval contains SPICE which broadly consistent expansion sulfidic, environments — indicating significant exacerbation an already-common condition Period. Additionally, speciation record local transition from predominantly anoxic, ferruginous (Fe+2 containing) euxinic (sulfide water column near initiation Trace abundances, however, appear decline before start SPICE, suggesting earlier global environments. More broadly, our modeling support notion portions remained deficient throughout portion Cambrian, also prone intervals more similar Oceanic Anoxic Events Mesozoic.

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ژورنال

عنوان ژورنال: Palaeogeography, Palaeoclimatology, Palaeoecology

سال: 2021

ISSN: ['1872-616X', '0031-0182']

DOI: https://doi.org/10.1016/j.palaeo.2021.110623