Redox-Assisted Osmium-Promoted C–C Bond Activation of Alkylnitriles
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چکیده
منابع مشابه
C‐H Bond Activation Reactions in Ketones and Aldehydes Promoted by POP‐Pincer Osmium and Ruthenium Complexes
The tetrahydride complex OsH4{xant(PPr2)2} (1, xant(PPr2)2 = 9,9-dimethyl-4,5bis(diisopropylphosphino)xanthene) activates an ortho-C-H bond of benzophenone and acetophenone to give the osmaisobenzofuran derivatives OsH{κ-C,O-[C6H4C(R)O]}{xant(PPr2)2} (R = Ph (2), CH3 (3)). The reaction of 1 with perdeuterated benzophenone leads to 2 partially protiated. The deuterium distribution in the latter ...
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ژورنال
عنوان ژورنال: Organometallics
سال: 2018
ISSN: 0276-7333,1520-6041
DOI: 10.1021/acs.organomet.8b00326