Recovery of Rare Earth Elements from the Leaching Solutions of Spent NdFeB Permanent Magnets by Selective Precipitation of Rare Earth Oxalates

نویسندگان

چکیده

After mechanical pre-treatment, the typical hydrometallurgical route of NdFeB magnet recycling starts with leaching in acidic solutions. However, due to high concentration iron ions solution, selective recovery rare earths from solution is challenging. In our work, precipitation earth oxalates as a potential separation method was proposed. The neodymium oxalate first tested on model solutions, which then followed by experimental tests carried out real solutions after magnets. form investigated use different amounts oxalic acid relation its stoichiometric amount. most efficient observed case where sulfuric used for leaching. resulted about 93% all present whereas Fe and other elements (Ni, Co, B) practically did not change. An increase 20% 40% more than amount (100%) led efficiency 96.7% 98.1%, respectively. 1.4 ratio caused 7% decrease concentration, suggests co-precipitation. order investigate possibility further increasing iron, an additional tested, oxidized Fe2+ Fe3+ before oxalates.

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ژورنال

عنوان ژورنال: Minerals

سال: 2023

ISSN: ['2075-163X']

DOI: https://doi.org/10.3390/min13070846