Reactivity of a nitrosyl ligand on dinuclear ruthenium hydrotris(pyrazolyl)borato complexes toward a NO molecule
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Reactivity of a nitrosyl ligand on dinuclear ruthenium hydrotris(pyrazolyl)borato complexes toward a NO molecule.
A cationic mononitrosyl dinuclear ruthenium complex was prepared by removing one NO ligand of a dicationic dinitrosyl ruthenium complex using NaN3. Reduction and oxidation reactions of the mononitrosyl complex led to the isolation of a neutral nitrosyl-bridged complex and a dicationic mononitrosyl complex, respectively, as expected from the cyclic voltammogram. According to the electron count, ...
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ژورنال
عنوان ژورنال: Dalton Transactions
سال: 2013
ISSN: 1477-9226,1477-9234
DOI: 10.1039/c3dt51319j