Reactions of Chlorine Gas on Benzaldehyde-di-n-alkyl Acetals

Reactions and Thermochemistry of Alkyl Ions, Cn H2n+1+ (n=1-8), in the Gas Phase

Our research program focuses on identifying reaction processes important for plasma enhancement of combustion systems. Recommendations for temperature and energy dependencies of key ion-molecule reactions are made based on the laboratory measurements described above. Thermodynamic data such as heat capacity, entropy, and enthalpy are not available as a function of temperature for many of the io...

Gas-phase reactions of cyclopropenylidene with protonated alkyl amines.

Vinylidene carbenes (C3H2) are of high interest to interstellar, combustion, and organic chemistry. Due to their high instability, the direct experimental investigation of their chemical reactivity has rarely been achieved. Herein, we report a first study on the reactions of cyclopropenylidene (c-C3H2) with protonated alkyl amines in the gas phase using a home-built ion trap mass spectrometer. ...

Inhalation of chlorine gas.

The clinical features of acute chlorine gas inhalation, and its management are reviewed. Current medical views on the chronic effects of an acute overwhelming exposure on lung function (reactive airways dysfunction syndrome), and the more controversial field of lung disease secondary to repeated inhalations of lower concentrations of chlorine gas are discussed.

Respiratory effects of chlorine gas.

Intermolecular addition reactions of N-alkyl-N-chlorosulfonamides to unsaturated compounds

N-Alkyl-N-chlorosulfonamides add to alkenes under copper(I) catalysis. In reactions of styrene derivatives with terminal double bonds the addition products were obtained in excellent yield and high regioselectivity. Lower yields are obtained in addition reactions to non-aromatic alkenes. The reaction most likely proceeds via a redox catalysis and amidyl radicals, a concerted mechanism has been ...