Reaction of Acetonedicarboxylic Acid with Acetic Anhydride. II.
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چکیده
منابع مشابه
he reaction rate of phithalic anhydride with urea in the presence of acetic acid from the freezing curve
antranilic acid is an intermediate material which we can produce by hofmann's rearrangement reaction. in this process phithalimide is a main reactant. one procedure for produceing phthalimide is the reaction of phithalic anhydride with urea in the presence of acetic acid. in this research, the kinetics of this reaction was studied at 115 c. we found that the reaction of phthalic anhydride ...
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Rat serum HDL was labeled by reaction with [3H] acetic anhydride at pH 7.2 for 30 min at room temperature by a modification of the method of Montelaro and Rueckert (1975. J. Biol. Chem. 250: 1413). Protein specific activities of 60 dpm/ng were achieved. Seven percent of the label was in lipid, of which 92 percent was recovered in phospholipid. The labeled HDL migrated as a single band as seen b...
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1. The extent of reaction of the protein with 3,3-tetramethyleneglutaric anhydride was measured by determining the loss of lysine and the equivalent appearance of 3,3-tetramethyleneglutarimidolysine in the hydrolysate at various time-intervals. Of the 19 lysine residues in sperm-whale myoglobin, three did not react with 3,3-tetramethyleneglutaric anhydride. Also, the N-terminal valine did not r...
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There are recorded in literature several instances in which the acylation of amino acids in the presence of pyridine proceeded abnormally. ’ We have encountered an unexpected reaction in attempting to acetylate I-tyrosine suspended in. a solution of pyridine in commercial acetic anhydride (containing 90 to 95 per cent of the pure anhydride). From the reaction product a orystalline substance, CM...
متن کاملFuran derivatives. 1С. Role of acetic anhydride in nitration of 3-(2-furyl)acryIic acid
An exothermic reaction, leading to 3-(2-furyl)acrylic anhydride and a little amount of furfurylideneacetone is taking place when reacting 3-(2-furyl)acrylic acid in acetic anhydride above 120°C. The 3-(5-acetyl-2-furyl)acrylic acid was formed under the afore-mentioned conditions only in the presence of H 3 P 0 4 . The 3-(2-furyl)acrylic anhydride is more stable towards HNO, at temperatures unde...
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ژورنال
عنوان ژورنال: YAKUGAKU ZASSHI
سال: 1967
ISSN: 0031-6903,1347-5231
DOI: 10.1248/yakushi1947.87.6_695