Reaction of 3-Methylindole with singlet oxygen
نویسندگان
چکیده
منابع مشابه
Computational Study of the Mechanism, Reaction Rate and Thermochemistry of Atmospheric Oxidation of Methylamine with Singlet Oxygen
The reaction of CH₃NH₂ with O₂ on the singlet potential energy surfaces (PES) was carried out using the B3LYP, CCSD(T) and G3B3 theoretical approaches along with 6-311++G(3df,3pd) basis set. The suggested mechanism for the title reaction consists of one pre-reactive complex. From the pre-reactive complex, nine types of products, CH2NH+H2O2, CH3NH+OOH,...
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On the basis of ab initio calculations we propose a revised mechanism for the reaction of organic sulfides with singlet oxygen, which is more consistent with experimental evidence than previous schemes. In aprotic solvents the reagents initially form a weakly bound peroxysulfoxide, with a small barrier due to entropy. The peroxysulfoxide may decay back to ground state (triplet) oxygen, be trapp...
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Spontaneous reactions between alkali metal or alkaline earth peroxides and hydrogen (deuterium) halide gases demonstrate the efficient production of singlet delta oxygen in a non-liquid medium. These reactions occur under ambient conditions without the need for any external energy source. The production of singlet delta oxygen was verified by direct emission spectroscopy at 1.27 microns with a ...
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Mn(TPP)Cl catalyzes cooxidation of olefin in the singlet oxygenation of sulfid. Mn(TPP)Cl is able to transfer an oxygen atom from a peroxidic intermediate generated in singlet oxygenation of sulfide to a metal ion affording metal 0x0 species which is responsible for epoxidation. This system leads to allcenes epoxidation such as styrene and cyclooctene. Epoxidation of cyclohexene produces cy...
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ژورنال
عنوان ژورنال: Australian Journal of Chemistry
سال: 1971
ISSN: 0004-9425
DOI: 10.1071/ch9711971