Rapid, One-Pot Synthesis of β-Siloxy-α-haloaldehydes
نویسندگان
چکیده
منابع مشابه
One-Pot Synthesis of β,β-Disubstituted α,β-Unsaturated Carbonyl Compounds.
TiCl4-promoted aldol reaction of ketones as aldol acceptors followed by elimination of the titanoxy group from the Ti-aldolates affords β,β-disubstituted α,β-unsaturated carbonyl compounds in a one-pot procedure. The use of additives, such as DMF, N,N,N',N'-tetramethylethylenediamine, and pyridine, in the elimination step was found to be important.
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ژورنال
عنوان ژورنال: Journal of the American Chemical Society
سال: 2011
ISSN: 0002-7863,1520-5126
DOI: 10.1021/ja2066169