Radical Reactions From Synthetic Viewpoint

Managing radical surgery: notes from the patient's viewpoint.

Based on a diary which was kept while preparing for and undergoing pan-proctocolectomy, the paper describes the process of coming to terms with an ileostomy. A number of stages in the process are identified: anticipation, reorientation, trauma, maintenance of selfimage and accommodation. The social-psychological strategies for coping with the process are elaborated.

The category of cpos from a synthetic viewpoint

We provide an internal characterization of the category Cpo of complete posets and continuous functions within the model H of SDT recently introduced by the authors It follows that cpos lie between the two extreme synthetic notions of domain given by repleteness and well completeness

The radical accuracy of the subjective viewpoint.

Nitrone-mediated radical coupling reactions: a new synthetic tool exemplified on dendrimer synthesis.

A synthetic strategy employing nitrones as radical spin traps is presented on the example of the efficient generation of novel dendrimers via a combination of radical and classical 'click' chemistry.

Radical thermochemistry and organic reactions*

Most free radicals are transient species and it is therefore difficult to measure their thermochemical properties. We have used two new techniques that address this problem. Photoacoustic calorimetry was used to measureheats of formation of free radicals and thus homolytic bond strengths, while photomodulated voltammetry was used to measure their oxidation and reduction potentials. The data off...