Quaternization reaction of 2-vinylpyridine and 4-vinylpyridine network copolymers for 4-nitrophenol adsorption
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چکیده
منابع مشابه
Origin of the Difference in Order-Disorder Transition Temperature between Polystyrene-block-poly(2-vinylpyridine) and Polystyrene-block-poly(4-vinylpyridine) Copolymers
Three polystyrene-block-poly(2-vinylpyridine) (S2VP diblock) and three polystyrene-block-poly(4-vinylpyridine) (S4VP diblock) copolymers with varying molecular weights and block compositions were synthesized via anionic polymerization, and their order-disorder transition temperatures (TODTs) were determined using oscillatory shear rheometry and small-angle X-ray scattering (SAXS). It has been f...
متن کاملSynthesis and Adsorption Properties of 4-Vinylpyridine and Styrene Copolymer In Situ Immobilized on Silica Surface
Copolymer of 4-vinylpyridine with styrene was in situ immobilized on silica gel surface via the heterogeneous radical polymerization. Anchorage of the copolymer on the surface layer was confirmed by IR spectroscopy. The quantity of copolymer on the silica gel surface was evaluated as 25.73 wt.% by TG and DSC-MS analysis. "Islet" location of polymer layer on the silica surface was confirmed by t...
متن کاملAdsorption of 4-Chloro-2-nitrophenol onto Nano-ZnO
Nano-ZnO was employed for the adsorption of 4C2NP from aqueous solutions in batch equilibriumexperiments to investigate its adsorption properties. The quantity of 4C2NP adsorbed onto nano- ZnOsurface was measured by UV-Vis spectrophotometer. The effects of contact time, adsorbent dose, pH, andinitial concentration of 4C2NP were investigated. The adsorption found to be strongly influenced by all...
متن کاملLooped Polymer Brushes Formed by Self-Assembly of Poly(2-vinylpyridine)-Polystyrene-Poly(2-vinylpyridine) Triblock Copolymers at the Solid-Fluid Interface. Kinetics of Preferential Adsorption
The kinetics of assembly of a series of poly(2-vinylpyridine)-polystyrene-poly(2-vinylpyridine) (PVP-b-PS-b-PVP) triblock copolymers from the selective solvent toluene onto a silicon surface has been studied using phase-modulated ellipsometry. The adsorbed amount and thickness have been determined independently as functions of time. Even though the adsorbed amount as a function of time follows ...
متن کاملPolyoxometalate-modulated self-assembly of polystyrene-block-poly(4-vinylpyridine).
Polyoxometalates can serve as active components to induce and modulate the micellization behavior of polystyrene-block-poly(4-vinylpyridine).
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ژورنال
عنوان ژورنال: Journal of the Brazilian Chemical Society
سال: 2007
ISSN: 0103-5053
DOI: 10.1590/s0103-50532007000200028