Quantification of hydrogen cyanide in fire effluent

نویسندگان

چکیده

Hydrogen cyanide is often the most toxicologically significant component in fire effluents from nitrogen-containing materials. Unlike other major asphyxiant, carbon monoxide, sensors for continuous hydrogen quantification, at and above dangerous concentrations, are not commercially available. This article investigates analysis of effluent captured bubbler solutions, by colorimetric quantification using chloramine-T/isonicotinic acid. The samples were mixed with reagents to give a blue dye response ions. A novel reaction scheme accounting formation ions presented. Dilute, standard solutions found be stable after storage up 1 year. Alkaline through which has passed, showed consistent stored between 5°C 21°C, 31 days sampling. effect common likely present solution (CO 3 2− , SO 4 NO 2 − ) was investigated their potential interference. interference sulphite reduced apparent concentration 13% 10 mg L −1 concentration.

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ژورنال

عنوان ژورنال: Journal of Fire Sciences

سال: 2023

ISSN: ['0734-9041', '1530-8049']

DOI: https://doi.org/10.1177/07349041231193756