Pulsed electric current sintering of TiB2-based ceramics using nitride additives

نویسندگان

چکیده

In this research, various types of nitride additives were incorporated into titanium diboride attaining dense TiB2-based ceramics by field-assisted sintering technique. The addition different additives, namely Si3N4, BN, AlN, and TiN, significantly improved the sinterability TiB2, achieving near fully ceramics. X-ray diffraction analysis microstructural evaluation confirmed presence h-BN compound in all specimens. TiB2-Si3N4 ceramic, Si3N4 additive reacted with B2O3 oxide, in-situ generating h-BN, SiO2 phases. Although phase was produced TiB2-AlN specimen, main proportion AlN remained sample as an unreacted ex-situ phase. terms TiB2-TiN some nitrogen boron atoms could leave TiN TiB2 crystalline structures, contributing to formation h-BN.

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ژورنال

عنوان ژورنال: Synthesis and sintering

سال: 2021

ISSN: ['2564-0186', '2564-0194']

DOI: https://doi.org/10.53063/synsint.2021.1112