Preparation of Higher Alkyl and Alkylphenyl Glycidyl Ethers
نویسندگان
چکیده
منابع مشابه
Solvent-Free Synthesis of Glycidyl Ethers Investigating Factors Influencing the Yield of Alkyl Glycidyl Ethers
Surfactants are a widely used group of chemicals. With a range of applications from soaps to paints and from hygiene products to asphalt they are one of the most diverse product groups available. AkzoNobel in Stenungsund uses glycidyl ethers as intermediates in the productions of some of their surfactants. These glycidyl ethers are produced with some hazardous compounds, which make the handling...
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6 aromatic glycidyl ethers containing naphthyl, biphenyl or benzylphenyl substituents were synthesized. These epoxides together with the commercially available compounds 2-biphenylyl glycidyl ether were examined for dose-mutagenicity relationships using the plate incorporation Ames test with Salmonella typhimurium strains TA100 and TA1535. Structure-mutagenicity relationships were further exami...
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The detoxication of the enantiomers of glycidyl 4-nitrophenyl ether (GNPE), (-)-(R)- and (+)-(S)-GNPE, and glycidyl 1-naphthyl ether (GNE), (-)-(R)- and (+)-(S)-GNE, by rat liver glutathione transferase and epoxide hydrolase was studied. Enantioselectivity was observed with both enzymes favoring the (R)-isomers as determined by the formation of conjugate, diol, and remaining substrate measured ...
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Antimitotic natural products that bind to cellular microtubules can be used as anticancer agents, and we are studying the cellular mechanisms of these compounds.1 The fungal metabolite phomopsin A is a key structure in these studies, and we are currently pursuing its synthesis.2 Our retrosynthetic analysis of phomopsin A targeted the chiral tertiary alkyl-aryl ether as a key disconnection withi...
متن کاملLabeled S-alkyl Glycerol Ethers and Derivatives
P, adioactive S-alkyl glycerol ethers have been synlhesized with 3SS, 14C and 3tt labels as well as 311/35S double labels. Tile synthesized compounds were converted to various derivatives which can serve to characterize tile S-alkyl glycerol ethers. These included tile isopropylidene derivative, oxidation with periodate to the aldehyde followed by reduction with LiAIH4 to tile alcohol, and reac...
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ژورنال
عنوان ژورنال: The Journal of the Society of Chemical Industry, Japan
سال: 1960
ISSN: 0023-2734,2185-0860
DOI: 10.1246/nikkashi1898.63.4_595