PREPARATION AND STRUCTURE/PROPERTY RELATIONSHIP OF POLYSULFONE ANION-EXCHANGE MEMBRANES

Polysulfone-based Anion Exchange Membranes for Potential Application in Solid Alkaline Fuel Cells

In present research work, anion exchange membranes based on quaternized polysulfone with ammonium cation moieties (QAPSF) were prepared by chloromethylation, amination and alkalization. The chloromethylated polysulfone were characterized by 1HNMR spectroscopy and functionalization degree was determined according to peak area integration. Ion transport properties (ionic conductivity, ion exchang...

Two-dimensional NMR spectroscopy reveals cation-triggered backbone degradation in polysulfone-based anion exchange membranes.

Anion exchange membranes (AEMs) find widespread applications as an electrolyte and/or electrode binder in fuel cells, electrodialysis stacks, flow and metal-air batteries, and electrolyzers. AEMs exhibit poor stability in alkaline media; their degradation is induced by the hydroxide ion, a potent nucleophile. We have used 2D NMR techniques to investigate polymer backbone stability (as opposed t...

Electrodialysis Heterogeneous Anion Exchange Membranes Filled with TiO2 Nanoparticles: Membranes' Fabrication and Characterization

In the current research, polyvinylchloride based mixed matrix heterogeneous anion exchange membranes were prepared by a solution casting technique. Titanium dioxide nanoparticles were also utilized as inorganic filler additive in the membrane fabrication. The effect of TiO2 nanoparticles concentration in the casting solution on the membrane physico-chemical properties was studied. Membrane wate...

Preparation and Evaluation of Anion-Exchange Polymer

PES/Quaternized-PES Blend Anion Exchange Membranes: Investigation of Polymer Compatibility and Properties of the Blend

Polyethersulfone (PES)-based anion exchange blend membranes were prepared from quaternized-PES (Q-PES) and N-Methyl-2-pyrrolidone (NMP) casting solutions with water as coagulant via non-solvent induced phase inversion. The compatibility of the blend system was investigated through thermodynamic studies while membrane formation was determined using the cloud point techni...