Pre-programmed self-assembly of polynuclear clusters
نویسندگان
چکیده
منابع مشابه
Non-additive simple potentials for pre-programmed self-assembly.
A major goal in nanoscience and nanotechnology is the self-assembly of any desired complex structure with a system of particles interacting through simple potentials. To achieve this objective, intense experimental and theoretical efforts are currently concentrated in the development of the so-called "patchy" particles. Here we follow a completely different approach and introduce a very accessi...
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S. A. Brown, J. G. Partridge, S. Scott, S. Hendy£, A. Ayesh, R. Reichel, K. C. Tee, M. Kaufmann, A. Awasthi£, P. Zoontjens£, A. Lassesson, J. van Lith, M. Schulze. # MacDiarmid Institute of Advanced Materials and Nanotechnology, † Nano Cluster Devices Ltd, Department of Physics and Astronomy, Rutherford Building, University of Canterbury, Christchurch, New Zealand Industrial Research Ltd, PO Bo...
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Nucleation and molecular aggregation are important processes in numerous physical and biological systems. In many applications, these processes often take place in confined spaces, involving a finite number of particles. Analogous to treatments of stochastic chemical reactions, we examine the classic problem of homogeneous nucleation and self-assembly by deriving and analyzing a fully discrete ...
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The thermodynamic self-assembly of any metallo-supramolecular complex [M(pm)L(pn)] in solution can be dissected into five additive free energy contributions. According to a hierarchical energetic order, the two microscopic describers f(inter) and f(intra), which refer to the hetero-component metal-ligand connections, bring the main driving forces to the complexation process. Combined with the s...
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ژورنال
عنوان ژورنال: Dalton Transactions
سال: 2018
ISSN: 1477-9226,1477-9234
DOI: 10.1039/c8dt00822a