Practical and Selective sp 3 C−H Bond Chlorination via Aminium Radicals
نویسندگان
چکیده
منابع مشابه
Synthesis of Arylamines via Aminium Radicals
Arylamines constitute the core structure of many therapeutic agents, agrochemicals, and organic materials. The development of methods for the efficient and selective construction of these structural motifs from simple building blocks is desirable but still challenging. We demonstrate that protonated electron-poor O-aryl hydroxylamines give aminium radicals in the presence of Ru(bpy)3 Cl2 . Thes...
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The title compound, C(9)H(12)NO(2) (+)·Cl(-), is the hydro-chloride of an N-substituted glycine derivative. The non-H atoms of the alkyl part of the mol-ecule lie nearly in a plane (r.m.s. deviation of all fitted non-H atoms = 0.0142 Å). In the crystal structure, O-H⋯Cl, N-H⋯Cl and C-H⋯O hydrogen bonds involving both O atoms as well as C-H⋯Cl contacts connect the components of the title compoun...
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ژورنال
عنوان ژورنال: Angewandte Chemie International Edition
سال: 2021
ISSN: 1433-7851,1521-3773
DOI: 10.1002/anie.202100030