Potentiometric determination of mephedrone in oral fluids with ion‐selective membranes

نویسندگان

چکیده

Abstract This work presents a potentiometric approach for the detection of two cathinone derivatives, namely mephedrone (4‐MMC) and clephedrone (4‐CMC). Contrary to neutral‐carriers (dibenzo‐18‐crown‐6‐ether calix[4]arene), cation‐exchanger (tetraphenylborate sodium) as active component ion‐selective membrane showed near‐Nernstian response (+47 mV/decade from 1.7 ⋅ 10 −6 5.6 −4 mol l −1 ) selectivity 4‐MMC in oral fluids (OF). The agreement between quantitative results obtained with HPLC/MS‐MS method determination OF shows potential proposed forensic analysis.

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ژورنال

عنوان ژورنال: Electroanalysis

سال: 2023

ISSN: ['1040-0397', '1521-4109']

DOI: https://doi.org/10.1002/elan.202200468