Porphyrin-modified DNA as Construction Material in Supramolecular Chemistry and Nano-architectonics

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Porphyrin-modified DNA as Construction Material in Supramolecular Chemistry and Nano-architectonics.

An overview is given on the developments of using porphyrin-modified DNA for the construction of functional assemblies. Strategies for the synthesis and characterisation are presented alongside selected applications where the porphyrin modification has proven to be particularly useful, but also revealed its limitations. We also discuss implications on property and behaviour of the porphyrin-DNA...

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Porphyrins and fullerenes are spontaneously attracted to each other. This supramolecular recognition element can be exploited to produce ordered arrays of interleaved porphyrins and fullerenes. C(60) x H(2)TpyP x Pb(NO(3))(2) x 1.5TCE (H(2)TpyP = tetra-4-pyridylporphyrin; TCE = 1,1,2,2-tetrachloroethane) crystallizes in the tetragonal P4/n space group and the structure has been solved to high r...

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ژورنال

عنوان ژورنال: CHIMIA International Journal for Chemistry

سال: 2015

ISSN: 0009-4293

DOI: 10.2533/chimia.2015.678