Polyolefin nanocomposites based on metallocene catalysts
نویسندگان
چکیده
منابع مشابه
Metallocene Based Polyolefin Nanocomposites
One of the most efficient and versatile ways to synthesize polyolefin nanocomposites is the in-situ polymerization of olefins in the presence of nano particles by metallocene catalysts. Metallocene/methylaluminoxane (MAO) catalysts are soluble in hydrocarbons and therefore they can be absorbed perfectly in solution onto the surface of particles or fibers and after addition of ethene or propene ...
متن کاملThe Influence of Ziegler-Natta and Metallocene Catalysts on Polyolefin Structure, Properties, and Processing Ability
50 years ago, Karl Ziegler and Giulio Natta were awarded the Nobel Prize for their discovery of the catalytic polymerization of ethylene and propylene using titanium compounds and aluminum-alkyls as co-catalysts. Polyolefins have grown to become one of the biggest of all produced polymers. New metallocene/methylaluminoxane (MAO) catalysts open the possibility to synthesize polymers with highly ...
متن کاملPolyolefin-Clay Nanocomposites from Olefin Polymerization between Clay Layers
This mini-review article addresses the development in synthesizing polyolefin/clay nanocomposites by olefin polymerization under catalysis of clay intercalated precatalysts in recent years. The review comprises three parts which focus on mainly the synthetic route, structural characterization, and properties of polyolefin/clay nanocomposites, respectively. Moreover, outlook for future research ...
متن کاملIN SITU SILICA SUPPORTED METALLOCENE CATALYSTS FOR ETHYLENE POLYMERIZATION
Bis(2-R-ind)ZrCl2 (R: H or phenyl) was supported on different types of silica by in situ impregnation method and used for ethylene polymerization. In this method, the step of catalyst loading on support was eliminated and common alkyl aluminum (triisobutylaluminum, TiBA) cocatalyst was used instead of expensive methyl aluminiumoxane (MAO) cocatalyst in the polymerization. The effect of surface ...
متن کاملStructure Development from Simultaneous Phase Separation and Crystallization of Metallocene Polyolefin Blends
Introduction Olefin polymers are the most widely used materials in the plastics industry today. To optimize their properties and processibility, blending is often used. This is particularly important for the metallocene-catalyst based polyolefins. By altering certain shear-thinning and strain-hardening characteristics, blending can enhance the processibility of the material. This is in addition...
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ژورنال
عنوان ژورنال: Annals of Advances in Chemistry
سال: 2021
ISSN: 2576-3768
DOI: 10.29328/journal.aac.1001022