Polymeric concentrated electrolyte enables simultaneous stabilization of electrode/electrolyte interphases for quasi?solid?state lithium metal batteries

نویسندگان

چکیده

To achieve next-generation lithium metal batteries (LMBs) with desirable specific energy and reliability, the electrolyte shown simultaneously high reductive stability toward anode oxidative high-voltage cathode is of great importance. Here, we report for first time that high-concentration bis(fluorosulfonyl)imide (LiFSI) initiates ring-opening polymerization 1,3-dioxolane in presence ethylene carbonate ethylmethyl to produce in-situ a novel polymeric concentrated quasi-solid (poly-CQSE). The unique poly-CQSE 10 M LiFSI forms mixed-lithiophobic-conductive LiF-Li3N solid interphase on anode, F-rich conformal LiNi0.5Co0.2Mn0.3O2 (NCM523) simultaneously. As result, not only enables stable Li plating/stripping metallic at sound Coulombic efficiency 95.3% without dendrite growth, but also cycling Li||NCM523 quasi-solid-state LMB capacity retention 94% over 100 cycles.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Lithium batteries: Improving solid-electrolyte interphases via underpotential solvent electropolymerization

Understanding the mechanism of formation of solid-electrolyte interphases (SEI) is key to the prospects of lithium metal batteries (LMB). Here, we investigate via cyclic voltammetry, impedance spectroscopy and chronoamperometry the role of kinetics in controlling the properties of the SEI generated from the reduction of propylene carbonate (PC, a typical solvent in LMB). Our observations are co...

متن کامل

A Review of Solid Electrolyte Interphases on Lithium Metal Anode

Lithium metal batteries (LMBs) are among the most promising candidates of high-energy-density devices for advanced energy storage. However, the growth of dendrites greatly hinders the practical applications of LMBs in portable electronics and electric vehicles. Constructing stable and efficient solid electrolyte interphase (SEI) is among the most effective strategies to inhibit the dendrite gro...

متن کامل

Role of surface oxides in the formation of solid-electrolyte interphases at silicon electrodes for lithium-ion batteries.

Nonaqueous solvents in modern battery technologies undergo electroreduction at negative electrodes, leading to the formation of a solid-electrolyte interphase (SEI). The mechanisms and reactions leading to a stable SEI on silicon electrodes in lithium-ion batteries are still poorly understood. This lack of understanding inhibits the rational design of electrolyte additives, active material coat...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: EcoMat

سال: 2023

ISSN: ['2567-3173']

DOI: https://doi.org/10.1002/eom2.12325