Polyiodide salts of thioamides
نویسندگان
چکیده
منابع مشابه
Extended structures of polyiodide salts of transition metal macrocyclic complexes.
The structures of five polyiodide salts, [Co([9]aneS3)2]I11 (1), [Ni([9]aneS3)2]I6 (2), [Ni([9]aneS3)2]I10 (3), [Pd([12]aneS4)]I6 (4) and [Pd([14]aneS4)]I10.MeCN (5), containing the template cations [Co([9]aneS3)2]3+, [Ni([9]aneS3)2]2+, [Pd([12]aneS4)]2+ and [Pd([14]aneS4)]2+ ([9]aneS3=1,4,7-trithiacyclononane, [12]aneS4=1,4,7,10-tetrathiacyclododecane, [14]aneS4=1,4,8,11-tetrathiacyclotetradec...
متن کاملMetabolism of thioamides by Ralstonia pickettii TA.
Information on bacterial thioamide metabolism has focused on transformation of the antituberculosis drug ethionamide and related compounds by Mycobacterium tuberculosis. To study this metabolism more generally, a bacterium that grew using thioacetamide as the sole nitrogen source was isolated via enrichment culture. The bacterium was identified as Ralstonia pickettii and designated strain TA. C...
متن کاملCorrelation Between Structure and Phonon Spectra of Linear Polyiodide Chains
Ramanand IR-spectra of four compounds of the general composition TlelöMj/",, (I4) \n: formal valence of the M-atom, M = Ag, Au, Pb and (Bio.sTlo.s)] were investigated in order to identify the polyiodide species present. In accordance with structural results comparable amounts of l4 2 and l3~/I~-groups were found for M = Ag, Pb and (Bio.sTlo.s), while in Tl6l6Au2(Li) I3_/I~groups predominate.
متن کاملThioamides in the collagen triple helix.
To probe noncovalent interactions within the collagen triple helix, backbone amides were replaced with a thioamide isostere. This subtle substitution is the first in the collagen backbone that does not compromise thermostability. A triple helix with a thioamide as a hydrogen bond donor was found to be more stable than triple helices assembled from isomeric thiopeptides.
متن کاملThe S-oxidation of thioamides by rat liver microsomes.
In the Vertebrates the two primary catalysts for the oxidation of xenobiotic sulphur-containing compounds appear to be the Flavin-containing monoxygenases. (FMO) and the cytochrome P-450 mooxygenases (P-450) [l]. The relative contribution of these enzyme systems to the oxidation of the vast majority of xenobiotics is unknown [l]. Thioamide compounds, such as thioacetamide, thiobenzamide , ethio...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section A Foundations of Crystallography
سال: 2011
ISSN: 0108-7673
DOI: 10.1107/s0108767311084819