Polyelectrolytes

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Highly-metallized phosphonium polyelectrolytes.

The synthesis and characterization of a novel class of highly-metallized, redox-active polyelectrolytes that employ phosphorus as a scaffold for the installation of transition metals is described. Pyrolysis of thin films of the title polyelectrolytes resulted in the production of magnetite crystallites and ill-defined carbon-, phosphorus- and oxygen-rich phases in char yields of nearly 50%.

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Michal Borkovec, Ger J. M. Koper Email. [email protected], [email protected] September 15, 2013 Direct link www.colloid.ch/polyelectrolytes In aqueous solutions, bases bind protons, while acids dissociate them. For weak acids and bases, these protonation reactions occur in the intermediate pH range. Dealing with monoprotic or diprotic acids and bases, the corresponding binding isoth...

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Interacting rigid polyelectrolytes

The persistence length of charged linear polymers in semidilute solution must increase substantially upon addition of salt. For very long polymers the persistence length increases as the salt concentration to the 5/2 power provided this salt concentration is not too large. In deriving this scaling we correct our previous prediction in light of a recent paper by Barrat and Joanny, and in agreeme...

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ژورنال

عنوان ژورنال: Kobunshi

سال: 1982

ISSN: 0454-1138,2185-9825

DOI: 10.1295/kobunshi.31.785