Photophysical Properties of Eu3+ β-Diketonates with Extended π-Conjugation in the Aromatic Moiety

نویسندگان

چکیده

The influence of the degree π-conjugation in biaroylmethane ligands upon Eu3+ luminescence efficiency corresponding neutral tris-complexes was investigated depth. data obtained by both steady-state and time-resolved measurements gave an inside into electronic energy transfer mechanisms abovementioned complexes. It shown that extension π-system naphthalene moiety comparison to phenyl one lead a substantial decrease S1 T1 symmetrical β-diketones, which, turn, led total quantum yield respective results are interest for rational design highly luminescent complexes with NIR-emitting lanthanides, as resonant levels energies low can hardly be sensitized common ligands.

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ژورنال

عنوان ژورنال: Inorganics (Basel)

سال: 2022

ISSN: ['2304-6740']

DOI: https://doi.org/10.3390/inorganics11010015