Photoisomerization of di-nuclear rhenium(i) bpe-based compounds
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چکیده
منابع مشابه
Photoisomerization kinetics of cefuroxime axetil and related compounds.
The photoisomerization kinetics of aqueous solutions of cefuroxime axetil under irradiation at 254 nm was investigated by HPLC. The overall degradation is the result of a competition between the isomerization of the alkoxyimino group and the photolysis of the beta-lactam ring. Cefuroxime axetil exists as a mixture of two diastereomers which are shown to react at different rates. This is true no...
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OBJECTIVE To investigate promoting factors for background parenchymal enhancement (BPE) in MR mammography (MRM). METHODS 146 patients were retrospectively evaluated, including 91 high-risk patients (50 BRCA patients, 41 patients with elevated lifetime risk). 56 screening patients were matched to the high-risk cases on the basis of age. The correlation of BPE with factors such as fibroglandula...
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Introduction: Bunched Phase Encoding (BPE) is a new type of fast data acquisition method in MRI that takes advantage of zigzag k-space trajectories along the PE direction (Fig.1)[1,2]. Sampling frequency of BPE is higher than that of normal acquisition. Since BPE acquisition scheme is comparable to acquiring multiple PE lines in a single readout, the total number of TR cycles and hence the scan...
متن کاملMono- and di-cationic hydrido boron compounds.
Brønsted acid HNTf2 (Tf = SO2CF3) mediated dehydrogenative hydride abstraction from (L(1))BH3 () and (L(2))BH3 () (L(1) = IPrCH2 = 1,3-(2,6-di-isopropylphenyl)imidazol-2-methylidene (); L(2) = SIPrCH2 = 1,3-(2,6-di-isopropylphenyl)imidazolidin-2-methylidiene ()) affords thermally stable hydride bridged mono-cationic hydrido boron compounds [{(L(1))BH2}2(μ-H)](NTf2) () and [{(L(2))BH2}2(μ-H)](NT...
متن کاملcomparison of catalytic activity of heteropoly compounds in the synthesis of bis(indolyl)alkanes.
heteropoly acids (hpa) and their salts have advantages as catalysts which make them both economically and environmentally attractive, strong br?nsted acidity, exhibiting fast reversible multi-electron redox transformations under rather mild conditions, very high solubility in polar solvents, fairly high thermal stability in the solid states, and efficient oxidizing ability, so that they are imp...
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ژورنال
عنوان ژورنال: Photochemical & Photobiological Sciences
سال: 2018
ISSN: 1474-905X,1474-9092
DOI: 10.1039/c8pp00274f