Photochemical Reaction of 1,3-Diketones. Transformation of 2-Benzoyl-2-methylcyclohexanones to 4-Benzoyl-2-methylcyclohexanones
نویسندگان
چکیده
منابع مشابه
2-Benzoyl-4-chloroaniline thiosemicarbazone
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متن کاملEthyl 2-(4-benzoyl-2,5-dimethylphenoxy)acetate
The title compound, C(19)H(20)O(4), was synthesized via a Fries rearrangement of hydr-oxy benzophenone. The dihedral angle between the least-squares planes of the two benzene rings is 69.04 (11)°. The mol-ecular structure displays an intra-molecular non-classical C-H⋯O hydrogen bond.
متن کاملEthyl N-(2-benzoyl-4-chlorophenyl)ethanecarboximidate
In the title compound, C(17)H(16)ClNO(2), the N=C-O-C-C fragment is planar within 0.029 (1) Å, and makes dihedral angles of 66.71 (8) and 59.61 (8)° with the planes of the chloro-phenyl and benzoyl rings, respectively. The carbonyl C=O bond is not coplanar with either of the aromatic rings; it makes angles of 42.5 and 23.5° with the normals to the ring planes. In the crystal, very weak C-H⋯O, C...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1990
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.63.935