Photochemical nitrogenation of alkanes and arenes by a strongly luminescent osmium(VI) nitrido complex
نویسندگان
چکیده
منابع مشابه
Catalytic oxidation of alkanes by a (salen)osmium(VI) nitrido complex using H2O2 as the terminal oxidant.
The osmium(VI) nitrido complex, [Os(VI)(N)(L)(CH3OH)](+) (1, L = N,N'-bis(salicylidene)-o-cyclohexyldiamine dianion) is an efficient catalyst for the oxidation of alkanes under ambient conditions using H2O2 as the oxidant. Alkanes are oxidized to the corresponding alcohols and ketones, with yields up to 75% and turnover numbers up to 2230. Experimental and computational studies are consistent w...
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ژورنال
عنوان ژورنال: Communications Chemistry
سال: 2019
ISSN: 2399-3669
DOI: 10.1038/s42004-019-0142-3