Pd-Catalyzed N-Formylation of Amines with N,N-Dimethylformamide
نویسندگان
چکیده
منابع مشابه
Formylation of amines.
Methods to convert amines to formamides are of interest due to the many uses of formamides as synthetic intermediates. These methods include stoichiometric reactions of formylating reagents and catalytic reactions with CO as the carbonyl source. This review discusses the reported stoichiometric and catalytic approaches for preparation of formamides.
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In recent years much effort has been carried out on formylations of amines. N-formyl compounds have been widely used in organic synthesis as protecting group of amines [1]. They are also used for synthesis of pharmaceutically important heterocylces [2-5]. Formamides are the Lewis bases, which are known to catalyze reactions such as allylations [6] and hydrosilylations [7] of carbonyl compounds....
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ژورنال
عنوان ژورنال: Chinese Journal of Organic Chemistry
سال: 2019
ISSN: 0253-2786
DOI: 10.6023/cjoc201809020