Palladium Catalyzed Reaction of Silacyclobutanes with Acetylenes

Palladium-Catalyzed, Enantioselective Heine Reaction

Aziridines are important synthetic intermediates for the generation of nitrogen-containing molecules. N-Acylaziridines undergo rearrangement by ring expansion to produce oxazolines, a process known as the Heine reaction. The first catalytic, enantioselective Heine reaction is reported for meso-N-acylaziridines where a palladium(II)-diphosphine complex is employed. The highly enantioenriched oxa...

Palladium-catalyzed cross-coupling reaction of azides with isocyanides.

An efficient palladium-catalyzed cross-coupling reaction of azides with isocyanides is developed, providing a general synthetic route to unsymmetric carbodiimides with excellent yields. This method shows a broad substrate scope, including not only aryl azides, but also unactivated benzyl and alkyl azides. Furthermore, from readily available substrates, Pd-catalyzed coupling with a tandem amine ...

Palladium-catalyzed Substitution Reaction of Allylic Derivatives with Tinacetylene.

The substitution reaction of allylic derivatives (acetate, carbonate, and chloride) with tinacetylene proceeded in the presence of palladium as a catalyst to give a product having a 1-ene-4-yne system.

Copper(I)-Catalyzed Coupling of Terminal Acetylenes with Aryl or Vinyl Halides Copper(I)-Catalyzed Coupling of Terminal Acetylenes

Hetrocyclization of Acetylenes with nitriles catalyzed by chromium Complex

A development of prospective synthetic methods to produce Pyridine including those of complex structure will allow to makes the latter more available and hence Pyridine bases will be widely used in industry. In this paper the Hetrocyclization of Acetylenes with nitriles catalyzed by chromium Complex has been carried out. We have limited our aim to study the chromium catalyzed activation of bifu...