Palladium-catalyzed reaction of allyl acetate, allyl benzoate, allyl chloride, allyl bromide, diallyl ether, and allyl alcohol with benzene.
نویسندگان
چکیده
منابع مشابه
Catalytic Stereospecific Allyl–Allyl Cross-Coupling of Internal Allyl Electrophiles with AllylB(pin)
Application of internal electrophiles in catalytic stereospecific allyl-allyl cross-coupling enable the rapid construction of multisubstituted 1,5-dienes, including those with all carbon quaternary centers. Compounds with minimal steric differentiation can be synthesized with high enantiomeric excess.
متن کاملIntramolecular coupling of allyl carboxylates with allyl stannanes and allyl silanes: a new type of reductive elimination reaction?
The palladium-catalyzed intramolecular coupling of allyl stannanes with allyl carboxylates provides a general synthesis of five- and six-membered-ring carbocycles. The intramolecular coupling leads selectively to trans five-membered carbocycles and cis six-membered carbocycles, regardless of the cis or trans configuration of the allylic functions in the starting material. For example, the stere...
متن کاملMechanism of allyl alcohol toxicity.
the OX-19 strain. A second strain of a Proteus sp., when inoculated into infusion broth containing penicillin, also produced large bodies. None of the bodies, however, were seen to revert to rods. Filtrates of such cultures were without activity in neutralizing the effect of the antibiotic. This second organism, however, grew profusely in the rod form in a broth-penicillin mixture to which acti...
متن کامل4-Allyl-4-ethylmorpholinium chloride
In the title molecular salt, C(9)H(18)NO(+)·Cl(-), the morpholine ring adopts a chair conformation. In the crystal structure, intra-molecular C-H⋯Cl bonds occur and inter-molecular C-H⋯O and C-H⋯Cl hydrogen bonds link the mol-ecules.
متن کاملCatalytic intermolecular allyl-allyl cross-couplings between alcohols and boronates.
We developed catalytic intermolecular C(sp(3))-C(sp(3)) cross-couplings between various allyl alcohols and allyl boronates, which proceeded smoothly in the presence of nickel(0) under mild conditions to form 1,5-dienes with excellent linear- and γ-selectivity; the use of boronates proved to be crucial in terms of reactivity.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: NIPPON KAGAKU KAISHI
سال: 1985
ISSN: 2185-0925,0369-4577
DOI: 10.1246/nikkashi.1985.512