Palladium and Nickel Catalyzed Chain Walking Olefin Polymerization and Copolymerization
نویسندگان
چکیده
منابع مشابه
Palladium(II)-catalyzed copolymerization of styrenes with carbon monoxide: mechanism of chain propagation and chain transfer.
A mechanistic interpretation of the [(1,10-phenanthroline)Pd(CH(3))(CH(3)CN)](+)[BArF](-) (1a) and [(2,2'-bipyridine)Pd(CH(3))(CH(3)CN)](+)[BArF](-) (1b) (BArF = 3,5-(CF(3))(2)-C(6)H(3)) catalyzed perfectly alternating copolymerization of styrenes with CO is reported. The copolymerization in CH(2)Cl(2) or chlorobenzene has been found to be first order in styrene and inverse first order in CO co...
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ژورنال
عنوان ژورنال: ACS Catalysis
سال: 2015
ISSN: 2155-5435,2155-5435
DOI: 10.1021/acscatal.5b02426