Oxidation of α-Trifluoromethyl and Nonfluorinated Secondary Alcohols to Ketones Using a Nitroxide Catalyst
نویسندگان
چکیده
Abstract A methodology for the oxidation of α-trifluoromethyl alcohols to corresponding trifluoromethyl ketones is presented. catalytic quantity a nitroxide used, and potassium persulfate serves as terminal oxidant. The proves effective aromatic, heteroaromatic, conjugated alcohol substrates. It can be extended nonfluorinated secondary and, in this case, applied range aliphatic alcohols.
منابع مشابه
NHCs Catalyzed Hydrophosphonylation of α-Ketoesters and α-Trifluoromethyl Ketones
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ژورنال
عنوان ژورنال: Synthesis
سال: 2023
ISSN: ['1791-5155', '1791-5856']
DOI: https://doi.org/10.1055/s-0042-1752398