One-pot electrosynthesis of ultrathin overoxidized poly(3,4-ethylenedioxythiophene) films

Electrochemical Characterisations of Ultra Thin Overoxidized Polypyrrole Films Obtained by One-Step Electrosynthesis

Ultra thin (10-20 nm) and pin-hole free overoxidized polypyrrole films were directly electrosynthezised under potentiostatic conditions in the presence of weak-acid anions, specifically monohydrogenophosphate. Various overoxidized polypyrrole membranes were fabricated in these conditions at different potentials in the range of 0.70 to 0.90 V/SCE. Their non-conductive property and blocking chara...

Virus-poly(3,4-ethylenedioxythiophene) biocomposite films.

Virus-poly(3,4-ethylenedioxythiophene) (virus-PEDOT) biocomposite films are prepared by electropolymerizing 3,4-ethylenedioxythiophene (EDOT) in aqueous electrolytes containing 12 mM LiClO(4) and the bacteriophage M13. The concentration of virus in these solutions, [virus](soln), is varied from 3 to 15 nM. A quartz crystal microbalance is used to directly measure the total mass of the biocompos...

Superparamagnetic ultrathin films

Wrinkling of Ultrathin Polymer Films

This paper presents a bilayer model to account for surface effects on the wrinkling of ultrathin polymer films. Assuming a surface layer of finite thickness, effects of surface properties on the critical strain, the equilibrium wavelength, and the wrinkle amplitude are discussed in comparison with conventional analysis. Experimental measurements of wrinkling in polymer films with thickness rang...

SPR of Ultrathin Organic Films

Surfaceplasmonresonance (SPR) methods are surface-sensitive spectroscopic techniques that can be used to characterize a variety of ultrathin organic monolayers and multilayers at gold, silver, and copper surfaces. For example, SPR measurements have been used to study Langmuir-Blodgett films {1-3), selfassembled organic monolayers (4,5), specifically and nonspecifically adsorbed biopolymers (inc...