On polyethylene chain generation through chemical crosslinking of isotactic polypropylene
نویسندگان
چکیده
منابع مشابه
The influence of chain defects on the crystallisation behaviour of isotactic polypropylene
The crystallization characteristics of the !-, "-and #-phases of isotactic polypropylene were studied for welldefined and fully characterized polymers with varying amounts of stereoand regio-defects. The specimens enabled us to study separately the influence of the type of chain defect and the concentration of defects on the parameters of interest. A combined defect fraction (CDF) was introduce...
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A filament stretching extensional rheometer with a custom-built oven was used to investigate the effect of uniaxial flow on the crystallization of polypropylene. Prior to stretching, samples were heated to a temperature well above the melt temperature to erase their thermal and mechanical histories and the Janeschitz-Kriegl protocol was applied. The samples were stretched at extension rates in ...
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Dispersions of isotactic polypropylene (PP) particles in polystyrene (PS) were produced by interfacially driven breakup of nanolayers in multilayered systems that were fabricated by means of layer-multiplying coextrusion. The droplet size was controlled by the individual PP layer thickness ranging from 12 to 200 nm. In addition, PP was melt blended with PS to produce PP droplets larger than tho...
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Bulk isotactic polypropylene in the a form was studied using density functional theory-based computations. The computed physical structure of this system is in excellent agreement with available experimental data. The electronic band structure, ionization potential, and electron affinity were also determined. The impact of various types of chemical imperfections (including double bond, hydroxyl...
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Polyethylene and polypropylene are the two polyolefins with wide ranging applications. They are recalcitrant and hence remain inert to degradation and deterioration leading to their accumulation in the environment, and, therefore creating serious environmental problems. In this review, biodegradation of these two polymers under in vitro conditions is reported. An attempt has been made to cover ...
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ژورنال
عنوان ژورنال: Journal of Applied Polymer Science
سال: 2009
ISSN: 0021-8995,1097-4628
DOI: 10.1002/app.30903