NOVEL MONONUCLEAR METAL-PHOSPHINITE COMPOUNDS AND CATALYTIC PERFORMANCE IN TRANSFER HYDROGENATION OF KETONES
نویسندگان
چکیده
Since the obtained chiral alcohols are rather useful as well biologically active compounds, reduction of ketones to their respective is a crucial topic in synthetic chemistry. Thus, new phosphinite ligand was synthesized by interaction cationic species N-vinyl imidazolium (1) with PCy2Cl. This combination [Ru(η6-p-cymene)(µ-Cl)Cl]2 and Ir(η5-C5Me5)(μ-Cl)Cl]2 gave catalytic systems for transfer hydrogenation reaction. Under optimum circumstances, ruthenium complex (3) showed high conversion reaction acetophenone. Reversibility found be low under these circumstances.
منابع مشابه
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ژورنال
عنوان ژورنال: Middle east journal of science
سال: 2022
ISSN: ['2618-6136']
DOI: https://doi.org/10.51477/mejs.1077805