Nonporous but yet Gas-Sorbing Molecular Crystals Formed by Macrocyclic Compounds with Nitrogen-Bridges

نویسندگان

چکیده

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Organo-nitrogen Compounds from Molecular Nitrogen

INTRODUCTION Industrial nitrogen fixation plays an important role in sustaining approximately 40% of the Earth’s population through generation of synthetic fertilizers. Annually, ca. 500 million tons of anhydrous ammonia, ammonium nitrate, and urea are produced through the Haber-Bosch process, which requires harsh conditions (200 atm, 450-500C) and affords low yields 10-20%. It has been estimat...

متن کامل

Fluorinated liquid crystals formed by halogen bonding.

New, halogen-bonded fluorinated mesogens are reported; the expected microphase separation associated with perfluoroalkyl chains is surprisingly absent in the mesophase.

متن کامل

Modeling molecular crystals formed by spin-active metal complexes by atom-atom potentials.

We apply the atom-atom potentials to molecular crystals of iron(II) complexes with bulky organic ligands. The crystals under study are formed by low-spin or high-spin molecules of Fe(phen)(2)(NCS)(2) (phen = 1,10-phenanthroline), Fe(btz)(2)(NCS)(2) (btz = 5,5',6,6'-tetrahydro-4H,4'H-2,2'-bi-1,3-thiazine), and Fe(bpz)(2)(bipy) (bpz = dihydrobis(1-pyrazolil)borate, and bipy = 2,2'-bipyridine). Al...

متن کامل

Modeling molecular crystals formed by spin-active metal complexes by atom–atom potentialsw

We apply the atom–atom potentials to molecular crystals of iron(II) complexes with bulky organic ligands. The crystals under study are formed by low-spin or high-spin molecules of Fe(phen)2(NCS)2 (phen = 1,10-phenanthroline), Fe(btz)2(NCS)2 (btz = 5,5 0,6,60-tetrahydro4H,40H-2,20-bi-1,3-thiazine), and Fe(bpz)2(bipy) (bpz = dihydrobis(1-pyrazolil)borate, and bipy = 2,20-bipyridine). All molecula...

متن کامل

Nitrogen-containing organic compounds and oligomers in secondary organic aerosol formed by photooxidation of isoprene.

Electrospray ionization high-resolution mass spectrometry (ESI HR-MS) was used to probe molecular structures of oligomers in secondary organic aerosol (SOA) generated in laboratory experiments on isoprene photooxidation at low- and high-NO(x) conditions. Approximately 80-90% of the observed products are oligomers and up to 33% by number are nitrogen-containing organic compounds (NOC). We observ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Nihon Kessho Gakkaishi

سال: 2013

ISSN: 0369-4585,1884-5576

DOI: 10.5940/jcrsj.55.37