Non-Catalytic Autoxidation of Paraffinic Hydrocarbon
نویسندگان
چکیده
منابع مشابه
Catalytic oxidation of alkanes by iron bispidine complexes and dioxygen: oxygen activation versus autoxidation.
Organic substrates (specifically cis-1,2-dimethylcyclohexane, DMCH) are oxidized by O2 in the presence of iron(II)-bispidine complexes. It is shown that this oxidation reaction is not based on O2 activation by the nonheme iron catalysts as in Nature but due to a radical-based initiation, followed by a radical- and ferryl-based catalytic reaction.
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ژورنال
عنوان ژورنال: The Journal of the Society of Chemical Industry, Japan
سال: 1962
ISSN: 0023-2734,2185-0860
DOI: 10.1246/nikkashi1898.65.9_1372