{N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ4N,N′,N′′,N′′′}(thiocyanato-κN)zinc(II) perchlorate
نویسندگان
چکیده
منابع مشابه
Perchlorato[N,N,N′,N′-tetrakis(2-pyridylmethyl)cyclohexane-1,2-diamine]manganese(II) perchlorate
The asymmetric unit of the title compound, [Mn(ClO(4))(C(30)H(34)N(6))]ClO(4), consists of a cationic [Mn(ClO(4))(C(30)H(34)N(6))](+) complex and a perchlorate anion. In the complex, the Mn(2+) ion is seven-coordinated in an approximately penta-gonal-bipyramidal environment by six N atoms from the hexa-dentate N,N,N',N'-tetra-kis(2-pyridylmeth-yl)-cyclo-hexane-1,2-diamine (tpdach) ligand and on...
متن کاملBis{N-methyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine}zinc bis(perchlorate)
The title mononuclear zinc(II) complex, [Zn(C(10)H(15)N(3))(2)](ClO(4))(2), was obtained by the reaction of 2-acetyl-pyridine, N-methyl-ethane-1,2-diamine and zinc perchlorate in methanol. The asymmetric unit of the complex contains two independent [Zn(C(10)H(15)N(3))(2)](2+) cations and four perchlorate anions. The Zn(II) atom in each complex cation is six-coordinated by two pyridine N, two im...
متن کامل[μ-N,N′-Bis(2-pyridylmethylene)ethane-1,2-diamine]bis{aqua[N,N′-bis(2-pyridylmethylene)ethane-1,2-diamine]manganese(II)} tetrakis(perchlorate)
The cation of the salt, [Mn(2)(C(14)H(14)N(4))(3)(H(2)O)(2)](ClO(4))(4), lies on a center of inversion, the center lying midway along the ethyl-ene chain of the bridging N,N'-bis-(2-pyridylmethyl-ene)ethane-1,2-diamine ligand. The Mn atom is chelated by two atoms N atoms of this bridging ligand, and is also coordinated by four N atoms of another ligand. The Mn atom is seven-coordinated in a pen...
متن کامل2-(Benzenesulfonamido)pyridinium perchlorate
In the title compound, C(11)H(11)N(2)O(2)S(+)·ClO(4) (-), the dihedral angle between the benzene and pyridinium rings is 87.33 (10)°. An intra-molecular N-H⋯O inter-action, with an S=O-bonded O atom as receptor, occurs in the cation. In the crystal structure, ion pairs occur, being linked by strong N-H⋯O hydrogen bonds. The perchlorate anion plays a further role in the mol-ecular packing by acc...
متن کامل2-Cyanoanilinium perchlorate
In the title compound, C(7)H(7)N(2) (+)·ClO(4) (-), the cation is almost planar (r.m.s. deviation = 0.042 Å). In the crystal structure, the cations and anions are linked into a two-dimensional network parallel to (100) by N-H⋯O hydrogen bonds.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2010
ISSN: 1600-5368
DOI: 10.1107/s1600536810021628