Nitration of p-cymene. Exchange and rearomatization reactions of p-cymene adducts
نویسندگان
چکیده
منابع مشابه
Tetraethylammonium trichlorido(η6-p-cymene)ruthenate(II)
In the title salt, [(C(2)H(5))(4)N][RuCl(3)(C(10)H(14))], the Ru(II) atom shows an octa-hedral coordination in which the aromatic ring of the p-cymene mol-ecule occupies three coordination positions.
متن کاملDichlorido(η6-p-cymene)(ethoxydiphenylphosphane)ruthenium(II)
The title compound, [RuCl2(C10H14)(C14H15OP)], is an Ru(II) complex in which an η(6)-p-cymene ligand, two chloride anions and the P atom of an ethoxydiphenylphosphane ligand form a piano-stool coordination environment about the central Ru(II) atom.
متن کاملUnusual dimer formation of cyclometalated ruthenium NHC p-cymene complexes.
We present the synthesis and structural characterization of novel ruthenium complexes containing C^C* cyclometalated N-heterocyclic carbene ligands, η(6)-arene (p-cymene) ligands and one bridging chlorine ion. Complexes of the general formula [Ru(p-cymene)(C^C*)Cl] were prepared via a one-pot synthesis using in situ transmetalation from the correspondent silver NHC complexes. These complexes re...
متن کاملEncapsulation process of p-Cymene into -Cyclodextrin: A Theoretical Study
A theoretical study using semi-empirical (PM3) and DFT calculations (B97D) was performed in both gas and aqueous phases, in order to obtain structural and energetic properties for the encapsulation process of p-Cymene into -cyclodextrin. Two modes of inclusion were assumed for the [p-Cym...-CD] host-guest complex: (i) Mode A, when the guest is placed in the hydrophobic cavity of the CD by the...
متن کامل(η6-p-Cymene)bis(trichloridostannyl)(triethoxyphosphine-κP)ruthenium(II)
In the title complex, [RuSn(2)(C(10)H(14))Cl(6)(C(6)H(15)O(3)P)], the Ru-Sn bond lengths [2.5619 (3) and 2.5669 (3) Å] are about 0.3 Å shorter than the sum of the covalent Ru and Sn radii (1.46 + 1.39 = 2.85 Å), in line with other structurally characterized arene ruthenium trichlorido-stannyl derivatives. The Ru(II) atom is surrounded by a para-cymene, a triethylphosphite and two trichloridosta...
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ژورنال
عنوان ژورنال: Canadian Journal of Chemistry
سال: 1976
ISSN: 0008-4042,1480-3291
DOI: 10.1139/v76-058