New fluorous/organic biphasic systems achieved by solvent tuning
نویسندگان
چکیده
منابع مشابه
Tuning solution polymer properties by binary water–ethanol solvent mixtures{
The solubility of polymers can be significantly altered by the use of solvent mixtures. The solvent composition also effects the self-assembly properties of amphiphilic copolymers. In addition, water–ethanol mixtures are known to exhibit abnormal physicochemical properties due to the presence of hydration shells around the ethanol molecules, while at the same time both solvents have very low to...
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The l 6 85 pseudo-wild type of lambda repressor fragment is a fast two-state folder (kf 35 msec 1 at 58°C). Previously, highly stable l 6 85 mutants with kf > 30 msec 1 have been engineered to fold nearly or fully downhill. Stabilization of the native state by solvent tuning might also tune l 6 85 away from two-state folding. We test this prediction by examining the folding thermodynamics and k...
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ژورنال
عنوان ژورنال: Tetrahedron
سال: 2007
ISSN: 0040-4020
DOI: 10.1016/j.tet.2007.06.092