Nanoarchitectonics for Coordination Asymmetry and Related Chemistry

Focus on Materials Nanoarchitectonics.

Supramolecular coordination chemistry

Highlights include the formation of ultra-large macrocycles with over 200 non-hundred atoms within a given cycle. The realisation that single molecule magnetic behaviour is not limited to molecules with high spin states. The connection of S = 1/2 cluster rings using a fragment that can switch on magnetic exchange between the clusters is extremely interesting for the synthesis of QBITs and elect...

Organozinc Coordination Chemistry and Catalytic Effects of Organozinc Coordination Compounds

A review of the present state of organozinc coordination chemistry. with special emphasis on compounds of the type RZnX is given. Their preparation as well as some factors determining their structure and stability are discussed. Certain organozinc coordination compounds have been found to be effective catalysts for cyclo-oligomerization and polymerization reactions. in particular of oxygen-cont...

Coordination Chemistry of Orotic acid

Our research group have been working on transistion metal complexes and their activity in the biology field, especially antimicrobial and anticancer properties. Novel pseudohalide ligands with orotic acid and its metal salt Ni(II) have been synthesized and evaluated for their antimicrobial activities by disc diffusion method. The complexes have been characterized by IR, SEM, Raman, P-Xrd and UV...

Chemistry of porous coordination polymers

Remarkable advances in the recent development of porous compounds based upon coordination polymers have paved the way toward functional chemistry having potential applications such as gas storage, separation, and catalysis. From the synthetic point of view, the advantage is a designable framework, which can readily be constructed from building blocks, the so-called bottom-up assembly. Compared ...