Nacre-Mimetic, Mechanically Flexible, and Electrically Conductive Silk Fibroin-MXene Composite Foams as Piezoresistive Pressure Sensors

نویسندگان

چکیده

The hierarchical nacre-like three-dimensional (3D) assembly of porous and lightweight materials is in high demand for applications such as sensors, flexible energy storage harvesting devices, electromagnetic interference shielding, biomedical applications. However, designing a biomimetic architecture highly challenging due to the lack experimental approaches achieve necessary control over materials’ microstructure on multilength scale. Aerogels foam-based have recently been developed attractive candidates pressure-sensing despite recent progress, bottleneck these electrical conductivity combined with mechanical flexibility fast strain recovery remains. In this study, first time, inspired by multiscale nacre, we fabricated series ultra-lightweight, flexible, electrically conductive, relatively high-strength composite foams through hybridizing cross-linked silk fibroin (SF) biopolymer, extracted from Bombyx mori silkworm cocoon, reinforced two-dimensional graphene oxide (GO) Ti3C2 MXene nanosheets. Nacre naturally material lightweight, mechanically robust network structure, thanks its 3D interconnected lamella-bridge micromorphology. Inspired material, assemble SF fibrous solution GO nanosheets into using bidirectional freeze-casting technique. Subsequent freeze-drying gas-phase hydrophobization resulted architectures unique combination resilience, conductance, ultra-lightness. presented excellent performances piezoresistive devices sorbents oil/water separation, which indicated great potential switchable electronics.

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ژورنال

عنوان ژورنال: ACS Applied Materials & Interfaces

سال: 2021

ISSN: ['1944-8244', '1944-8252']

DOI: https://doi.org/10.1021/acsami.1c09675