Multidentate Ligand Kinetics. I. The Ligand Substitution Reaction between Ethylenediaminetetraacetatocuprate(II) and Triethylenetetraminezinc(II)
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Kinetics and Mechanism of the Substitution of Ligand (Urea) of [Ti(ur)6]3+ by H2O and SCN¯ in Ethanol Solution
The kinetics of substitution of [Ti(ur)6]3+ by H2O and SCN¯ ion in ethanol solution have been measured spectrophotometrically by stopped-flow method. Water is a good nucleophile toward Ti(III) substrates. Even the solvent ethanol appears to be a poor ligand when compared to water. Substitution, in general follows two parallel pathways: "direct" (second order...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1975
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.48.3581