Microwave-assisted synthesis of highly dispersed ZrO2 on CNTs as an efficient catalyst for producing 5-hydroxymethylfurfural (5-HMF)

نویسندگان

چکیده

This work presents an efficient method of supporting zirconia (ZrO2) on COOH functionalized multi-walled carbon nanotubes (ZrO2/MWCNTs(C)) via a microwave (MW)-assisted method, which can be used as catalyst for converting fructose to 5-HMF. The developed composite by the MW-assisted route shows highly dispersed ZrO2 with small sizes 4–5 nm support, could not achieved conventional hydrothermal synthesis. Characterization unique amorphous structure was ascribed special interaction between support and MW irradiation. Specifically, MWCNTs were heated selectively due their strong MW-absorbing ability, led formation microscopic “hot spots”, enabling rapid synthesis (8 min) smaller hot surface MWCNTs. Conversely, under heating, nucleation rate slow prone form agglomerated particles support. contributed excellent activity ZrO2/MWCNTs(C) in conversion In detail, 5-HMF yield at ~72.8% ~62.9%, respectively, prepared whilst they are only about 24.7% 15.7% over

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ژورنال

عنوان ژورنال: Fuel Processing Technology

سال: 2022

ISSN: ['1873-7188', '0378-3820']

DOI: https://doi.org/10.1016/j.fuproc.2022.107292