Methyl 5-bromo-2-chloropyridine-3-carboxylate

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Methyl 5-bromo-2-chloro­pyridine-3-carboxyl­ate

The title compound, C(7)H(5)BrClNO(2), crystallizes with two independent molecules in the asymmetric unit. In the absence of classical inter-molecular inter-actions, the crystal structure exhibits relatively short inter-molecular Br⋯O distances [3.143 (9) and 3.162 (9)Å].

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5-Bromo-3-(3-fluoro­phenyl­sulfin­yl)-2-methyl-1-benzofuran

In the title compound, C(15)H(10)BrFO(2)S, the 3-fluoro-phenyl ring makes a dihedral angle of 85.0 (1)° with the mean plane [r.m.s. deviation = 0.008 (2) Å] of the benzofuran fragment. In the crystal, mol-ecules are linked by weak C-H⋯O hydrogen bonds and a Br⋯O contact [3.200 (3) Å]. The crystal structure also exhibits slipped π-π inter-actions between the benzene and furan rings of neighbouri...

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5-Bromo-2-methyl-3-(3-methyl­phenyl­sulfin­yl)-1-benzo­furan

In the title compound, C16H13BrO2S, the dihedral angle between the mean plane [r.m.s. deviation = 0.012 (1) Å] of the benzo-furan ring system and the 3-methyl-phenyl ring is 84.83 (4)°. In the crystal, mol-ecules are linked via pairs of Br⋯O [3.240 (1) Å] contacts, forming inversion dimers. These dimers are linked by C-H⋯π inter-actions, forming a three-dimensional network.

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Methyl 5-bromo-2-hy­droxy­benzoate

The title compound, C(8)H(7)BrO(3), is almost planar (r.m.s. deviation for the non-H atoms = 0.055 Å). In the crystal, O-H⋯O hydrogen bonds link the mol-ecules into C(6) chains propagating in [010]. Very weak aromatic π-π inter-actions [centroid-centroid distances = 3.984 (5) and 3.982 (5) Å] also occur.

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5-Bromo-3-(4-fluoro­phenyl­sulfon­yl)-2-methyl-1-benzofuran

In the title compound, C(15)H(10)BrFO(3)S, the 4-fluoro-phenyl ring makes a dihedral angle of 76.51 (6)° with the plane of the benzofuran fragment. In the crystal, mol-ecules are linked by weak non-classical inter-molecular C-H⋯O hydrogen bonds and an aromatic π-π inter-action between the benzene rings of neighbouring mol-ecules [centroid-centroid distance = 3.540 (3) Å].

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2008

ISSN: 1600-5368

DOI: 10.1107/s1600536808013305