Methyl 3-O-α-D-mannopyranosyl β-D-glucopyranoside tetrahydrate

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Methyl 3-O-α-d-mannopyranosyl β-d-glucopyran­oside tetra­hydrate

The title compound, C(13)H(24)O(11)·4H(2)O, forms extended hydrogen-bonded networks. These are present between disaccharides, but not as inter-residue hydrogen bonds, as well as to water mol-ecules that in addition form an inter-molecular chain of hydrogen bonds. The conformation of the disaccharide is described by the glycosidic torsion angles ϕ(H) = -34° and ψ(H) = -5°. Macroscopically, the d...

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Methyl 3-O-α-l-fucopyranosyl β-d-glucopyran­oside tetra­hydrate

The title compound, C(13)H(24)O(10)·4H(2)O, is the methyl glycoside of a disaccharide structural element present in the backbone of the capsular polysaccharide from Klebsiella K1, which contains only three sugars and a substituent in the polysaccharide repeating unit. The conformation of the title disaccharide is described by the glycosidic torsion angles ϕ(H) = 51.1 (1)° and ψ(H) = 25.8 (1)°. ...

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Methyl 2-acetamido-2-deoxy-β-D-glucopyranoside dihydrate and methyl 2-formamido-2-deoxy-β-D-glucopyranoside.

Methyl 2-acetamido-2-deoxy-β-D-glucopyranoside (β-GlcNAcOCH(3)), (I), crystallizes from water as a dihydrate, C(9)H(17)NO(6)·H(2)O, containing two independent molecules [denoted (IA) and (IB)] in the asymmetric unit, whereas the crystal structure of methyl 2-formamido-2-deoxy-β-D-glucopyranoside (β-GlcNFmOCH(3)), (II), C(8)H(15)NO(6), also obtained from water, is devoid of solvent water molecul...

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Anti-Anxiety Effect of (-)-Syringaresnol-4-O-β-d-apiofuranosyl-(1→2)-β-d-glucopyranoside from Albizzia julibrissin Durazz (Leguminosae).

Albizzia julibrissin Durazz, a Chinese Medicine, is commonly used for its anti-anxiety effects. (-)-syringaresnol-4-O-β-d-apiofuranosyl-(1→2)-β-d-glucopyranoside (SAG) is the main ingredient of Albizzia julibrissin Durazz. The present study investigated the anxiolytic effect and potential mechanisms on the HPA axis and monoaminergic systems of SAG on acute restraint-stressed rats. The anxiolyti...

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Methyl 3-O-α-l-fucopyranosyl α-d-gal­acto­pyran­oside: a synchrotron study

The title compound, C(13)H(24)O(10) is the methyl glycoside of a structural element α-l-Fucp-(1→ 3)-α-d-Galp making up two thirds of the repeating unit in the capsular polysaccharide of Klebsiella K63. The conformation of the title compound is described by the glycosidic torsion angles ϕ(H) = 55 (1)° and ψ(H) = -24 (1)°. The hy-droxy-methyl group in the galactose residue is present in the gauch...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2008

ISSN: 1600-5368

DOI: 10.1107/s1600536808021454