Metal fluoride promoted catalytic hydrogenation of aromatic nitro compounds over RANEY® Ni
نویسندگان
چکیده
منابع مشابه
Liquid-phase Catalytic Transfer Hydrogenation of Aromatic Nitro Compounds over Nickel-doped Carbon Catalysts
Ni-doped carbon aerogel catalysts were prepared through sol-gel polycondensation of furfural with resorcinol in the presence of nickel nitrate salts, followed by drying at ambient pressure and then carbonization in N2. The catalysts were used for catalytic transfer hydrogenation of aromatic nitro compounds with propan-2-ol as hydrogen donor and KOH as promoter, and have been found to exhibit ex...
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A new catalytic application of hypoiodite reagents generated in situ from iodide ions is found, which succeeded in the synthesis of bisbenzannelated spiroketal cores for the first time. Fluoride was proven to be obligatory for this spiroketalization, which is the first fluoride-promoted oxidative cycloetherification to aromatic spiroketals.
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ژورنال
عنوان ژورنال: RSC Advances
سال: 2015
ISSN: 2046-2069
DOI: 10.1039/c5ra02725j