منابع مشابه
Metal complexes in molecular junctions.
The use of metal complexes to achieve a conductive molecular junction with a special focus on organometallics is overviewed and illustrated with representative examples. The prospects offered by such compounds owing to their specific properties are discussed.
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Metal nanowires containing in-wire monolayer junctions of 16-mercaptohexanoic acid were made by replication of the pores of 70 nm diameter polycarbonate track etch membranes. Au was electrochemically deposited halfway through the 6 microm long pores and a self-assembled monolayer (SAM) of 16-mercaptohexadecanoic acid was adsorbed on top. A thin layer of Au was then electrolessly grown to form a...
متن کاملSynthesis, biological and molecular modeling studies of macrocyclic complexes of trivalent metal ions
The macrocyclic complexes of biological importance with power transition metals are synthesized by template methodology leading to the formation of the complex [MLX] X2; where L is macrocyclic ligand derived from 3,4-diaminotoluene, 2,4-thiazolidinedione, M=Cr (III) and Fe(III) X is Cl-, CH3COO- or NO3_.Characterisation of these complexes are through with the assistance of elemental analyses(CH...
متن کاملDissipation in molecular junctions.
A recently developed theory that formulates the phenomena of inelastic transport and current-driven dynamics in molecular-scale electronics within a time-dependent scattering approach is extended to account for dissipation of the current-induced excitation through coupling to electrode phonons and electron-hole pairs. Our approach treats the electronic transport, the nuclear dynamics, and the e...
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ژورنال
عنوان ژورنال: Dalton Transactions
سال: 2013
ISSN: 1477-9226,1477-9234
DOI: 10.1039/c3dt51487k