Mesoscale Simulations of Surfactant Dissolution and Mesophase Formation
نویسندگان
چکیده
منابع مشابه
Mesoscale simulations of surfactant dissolution and mesophase formation.
The evolution of the contact zone between pure surfactant and solvent has been studied by mesoscale simulation. It is found that mesophase formation becomes diffusion controlled and follows the equilibrium phase diagram adiabatically almost as soon as individual mesophases can be identified, corresponding to times in real systems of order 10 micros.
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Shear-induced orientation of a rigid surfactant mesophase.
An optically clear, crystalline, gel-like mesophase is formed by the addition of water to a micellar solution consisting of a mixture of 0.85 M anionic surfactant sodium bis(2-ethylhexyl) sulfosuccinate (AOT) and a 0.42 M zwitterionic surfactant phosphatidylcholine (lecithin) in isooctane. At 25 degrees C and water to AOT molar ratio of 70, the system has a columnar hexagonal microstructure wit...
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ژورنال
عنوان ژورنال: Physical Review Letters
سال: 2002
ISSN: 0031-9007,1079-7114
DOI: 10.1103/physrevlett.89.148302